Publications
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Prior to University of Pittsburgh
26. Bartholomew, A. K.;† Teesdale, J. J.; Hernández Sánchez,R.; Malbrecht, B.J.; Juda, C. E.; Ménard, G.; Bu, W.; Iovan, D. A.; Mikhailine, A. A.; Zheng, S.-L.; Sarangi, R.; Wang, S. G.; Chen, Y.-S.; Betley, T.A. "Resolving redox inequivalence within isovalent clusters: exposing the inadequacy of redox formalisms". Submitted.
25. Milton, M.; Schuster, N.; Paley, D. W.; Hernández Sánchez, R.; Ng, F.; Steigerwald, M. L.; Nuckolls, C. “Defying Strain in the Synthesis of an Electroactive Bilayer Helicene”. Chem. Sci. 2019, 10, 1029.
24. Hernández Sánchez, R.; Betley, T. A. “Thermally persistent high spin ground states in octahedral iron clusters”. J. Am. Chem. Soc. 2018, 140, 16792.
23. Hernández Sánchez, R.*; Champsaur, A. M.; Paley, D. W.; Choi, B.; Wang, S. G.; Bu, W.; Roy, X.; Chen. Y.-S.*; Steigerwald, M. L.*; Nuckolls, C*. “Electron cartography in clusters”. Angew. Chem. Int. Ed. 2018, 57, 13815.
22. Schuster, N.; Hernández Sánchez, R.; Bukharina, D.; Kotov, N. A.; Berova, N.; Ng, F.; Steigerwald, M. L.; Nuckolls, C. “A Helicene Nanoribbon with Greatly Amplified Chirality”. J. Am. Chem. Soc. 2018, 140, 6235.
21. Zhang, B.;§ Hernández Sánchez, R.;§ Zhong, Y.; Ball, M.; Terban, M. W.; Paley, D.; Billinge, S. J. L.; Ng, F.; Steigerwald, M. L.; Nuckolls, C. “Hollow Organic Semiconductors Assemble into Cellular Semiconductors”. Nat. Commun. 2018, 9, 1957. § = equal contribution.
20. Milton, M.; Cheng, Q.; Yang, Y.*; Nuckolls, C.*; Hernández Sánchez, R.*; Sisto, T.* “Molecular Materials for Nonaqueous Flow Batteries with a High Coulombic Efficiency and Stable Cycling”. Nano Lett. 2017, 17, 7859.
19. Keener, M.; Peterson, M.; Hernández Sánchez, R.; Oswald, V. F.; Wu, G.; Ménard, G.*. “Towards Catalytic Ammonia Oxidation to Dinitrogen: A Synthetic Cycle Using a Simple Manganese Complex”. Chem. Eur. J. 2017, 23, 11479.
18. Amiri, H.; Shepard, K.*; Nuckolls, C.*; Hernández Sánchez, R.*. “Single-Walled Carbon Nanotubes: Mimics of Biological Ion Channels”. Nano Lett. 2017, 17, 1204.
17. Lee, H.; Campbell, M. G.; Hernández Sánchez, R.; Börgel, J.; Raynaud, J.; Parker, S. E.; Ritter, T. “Mechanistic Insight Into High-Spin Iron(I)-Catalyzed Butadiene Dimerization”. Organometallics 2016, 35, 2923.
16. Furneaux, A. G.; Piro, N. A.; Hernández Sánchez, R.; Garmigna, K. M.; Fey, N.; Robinson, M. J.; Kassel, W. S.; Nataro, C. “Specroscopic, structural and computational analysis of [Re(CO)3(dippM)Br]n+ (dippM = 1,1’-bis(diiso-propylphosphino)metallocene, M = Fe, n = 0 or 1; M = Co, n = 1)”. Dalton Trans. 2016, 45, 4819.
15. Blass, B. L.; Hernández Sánchez, R.; Decker, V. A.; Robinson, M. J.; Piro, N. A.; Kassel, W. S.; Diaconescu, P. L.; Nataro, C. “Structural, Computational, and Spectroscopic Investigation of [Pd(k3-1,1’-bis(di-tert-butylphosphino)ferrocenediyl)X]+ (X = Cl, Br, I) Compounds”. Organometallics 2016, 35, 462.
14. Hernández Sánchez, R.; Bartholomew, A.; Powers, T.; Ménard, G.; Betley, T. A. “Maximizing electron exchange in a [Fe3] cluster”. J. Am. Chem. Soc. 2016, 138, 2235.
13. Hernández Sánchez, R.; Betley, T. A. “Meta-Atom Behavior in Clusters Revealing Large Spin Ground States”. J. Am. Chem. Soc. 2015, 137, 13949.
12. Hernández Sánchez, R.; Zheng, S.-L.; Betley, T. A. “Ligand Field Strength Mediates Electron Delocalization in Octahedral [(HL)2Fe6(L’)m]n+ Clusters”. J. Am. Chem. Soc. 2015, 137, 11126.
11. Hernández Sánchez, R.; Willis, A. M.; Zheng, S.-L.; Betley, T. A. “Synthesis of Well-Defined Bicapped Octahedral Iron Clusters [(trenL)2Fe8(PMe2Ph)2]n (n = 0, –1)”. Angew. Chem. Int. Ed. 2015, 54, 12009.
10. Cramer, S. A.; Hernández Sánchez, R.; Brakhage, D. F.; Jenkins, D. M. “Probing the role of an FeIV tetrazene in catalytic aziridination”. Chem. Commun. 2014, 50, 13967.
9. Wu, B.; Hernández Sánchez, R.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M. “Formation of a Heterobimetallic Zirconium/Cobalt Diimido Complexes via a Four-Electron Transformation”. Inorg. Chem. 2014, 53, 10021.
8. Powers, T. M.; Gu, N. X.; Fout, A. R.; Baldwin, A. M.; Hernández Sánchez, R.; Alfonso, D. M.; Chen, Y.-S.; Zheng, S.-L; Betley, T. A. “Synthesis of Open-Shell, Bimetallic Mn/Fe Trinuclear Clusters”. J. Am. Chem. Soc. 2013, 135, 14448.
7. Eames, E.; Hernández Sánchez, R.; Betley, T. A. “Metal atom lability in polynuclear complexes”. Inorg. Chem. 2013, 56, 5006.
6. Kraft, S. J.; Hernández Sánchez, R.; Hock, A. S. “A Remarkably Active Iron Catecholate Immobilized in a Porous Organic Polymer”. ACS Catal. 2013, 3, 826.
5. Wong, L. J.; Hernández Sánchez, R.; Glancy Logan, J.; Zarkesh, R. A.; Ziller, J. W.; Heyduk, A. F. “Disulfide reductive elimination from an iron(III) complex”. Chem. Sci. 2013, 4, 1906.
4. Harris, T. D.; Zhao, Q.; Hernández Sánchez, R.; Betley, T. A. “Expanded Redox Accessibility via Ligand Substitution in an Octahedral Fe6Br6 Cluster”. Chem. Commun. 2011, 47, 6344.
3. Yamazaki, Y.; Hernandez-Sanchez, R.; Haile, S. M. “Cation nonstoichiometry in yttrium-doped barium zirconate: phase behavior, microstructure, and proton conductivity”. J. Mater. Chem. 2010, 20, 8158-8166.
2. Telila, H.; Mamo, T.; Hernandez Sanchez, R. “The Fabrication of nanoparticle CsH2PO4 Electrolyte for Fuel Cell Applications”. Caltech Undergraduate Research Journal 2009, 9 (No. 1), 33 – 39.
1. Yamazaki, Y.; Hernandez-Sanchez, R.; Haile, S. M. “High Total Proton Conductivity in Large-Grained Yttrium-Doped Barium Zirconate”. Chem. Mater. 2009, 21, 2755-2762.
25. Milton, M.; Schuster, N.; Paley, D. W.; Hernández Sánchez, R.; Ng, F.; Steigerwald, M. L.; Nuckolls, C. “Defying Strain in the Synthesis of an Electroactive Bilayer Helicene”. Chem. Sci. 2019, 10, 1029.
24. Hernández Sánchez, R.; Betley, T. A. “Thermally persistent high spin ground states in octahedral iron clusters”. J. Am. Chem. Soc. 2018, 140, 16792.
23. Hernández Sánchez, R.*; Champsaur, A. M.; Paley, D. W.; Choi, B.; Wang, S. G.; Bu, W.; Roy, X.; Chen. Y.-S.*; Steigerwald, M. L.*; Nuckolls, C*. “Electron cartography in clusters”. Angew. Chem. Int. Ed. 2018, 57, 13815.
22. Schuster, N.; Hernández Sánchez, R.; Bukharina, D.; Kotov, N. A.; Berova, N.; Ng, F.; Steigerwald, M. L.; Nuckolls, C. “A Helicene Nanoribbon with Greatly Amplified Chirality”. J. Am. Chem. Soc. 2018, 140, 6235.
21. Zhang, B.;§ Hernández Sánchez, R.;§ Zhong, Y.; Ball, M.; Terban, M. W.; Paley, D.; Billinge, S. J. L.; Ng, F.; Steigerwald, M. L.; Nuckolls, C. “Hollow Organic Semiconductors Assemble into Cellular Semiconductors”. Nat. Commun. 2018, 9, 1957. § = equal contribution.
20. Milton, M.; Cheng, Q.; Yang, Y.*; Nuckolls, C.*; Hernández Sánchez, R.*; Sisto, T.* “Molecular Materials for Nonaqueous Flow Batteries with a High Coulombic Efficiency and Stable Cycling”. Nano Lett. 2017, 17, 7859.
19. Keener, M.; Peterson, M.; Hernández Sánchez, R.; Oswald, V. F.; Wu, G.; Ménard, G.*. “Towards Catalytic Ammonia Oxidation to Dinitrogen: A Synthetic Cycle Using a Simple Manganese Complex”. Chem. Eur. J. 2017, 23, 11479.
18. Amiri, H.; Shepard, K.*; Nuckolls, C.*; Hernández Sánchez, R.*. “Single-Walled Carbon Nanotubes: Mimics of Biological Ion Channels”. Nano Lett. 2017, 17, 1204.
17. Lee, H.; Campbell, M. G.; Hernández Sánchez, R.; Börgel, J.; Raynaud, J.; Parker, S. E.; Ritter, T. “Mechanistic Insight Into High-Spin Iron(I)-Catalyzed Butadiene Dimerization”. Organometallics 2016, 35, 2923.
16. Furneaux, A. G.; Piro, N. A.; Hernández Sánchez, R.; Garmigna, K. M.; Fey, N.; Robinson, M. J.; Kassel, W. S.; Nataro, C. “Specroscopic, structural and computational analysis of [Re(CO)3(dippM)Br]n+ (dippM = 1,1’-bis(diiso-propylphosphino)metallocene, M = Fe, n = 0 or 1; M = Co, n = 1)”. Dalton Trans. 2016, 45, 4819.
15. Blass, B. L.; Hernández Sánchez, R.; Decker, V. A.; Robinson, M. J.; Piro, N. A.; Kassel, W. S.; Diaconescu, P. L.; Nataro, C. “Structural, Computational, and Spectroscopic Investigation of [Pd(k3-1,1’-bis(di-tert-butylphosphino)ferrocenediyl)X]+ (X = Cl, Br, I) Compounds”. Organometallics 2016, 35, 462.
14. Hernández Sánchez, R.; Bartholomew, A.; Powers, T.; Ménard, G.; Betley, T. A. “Maximizing electron exchange in a [Fe3] cluster”. J. Am. Chem. Soc. 2016, 138, 2235.
13. Hernández Sánchez, R.; Betley, T. A. “Meta-Atom Behavior in Clusters Revealing Large Spin Ground States”. J. Am. Chem. Soc. 2015, 137, 13949.
12. Hernández Sánchez, R.; Zheng, S.-L.; Betley, T. A. “Ligand Field Strength Mediates Electron Delocalization in Octahedral [(HL)2Fe6(L’)m]n+ Clusters”. J. Am. Chem. Soc. 2015, 137, 11126.
11. Hernández Sánchez, R.; Willis, A. M.; Zheng, S.-L.; Betley, T. A. “Synthesis of Well-Defined Bicapped Octahedral Iron Clusters [(trenL)2Fe8(PMe2Ph)2]n (n = 0, –1)”. Angew. Chem. Int. Ed. 2015, 54, 12009.
10. Cramer, S. A.; Hernández Sánchez, R.; Brakhage, D. F.; Jenkins, D. M. “Probing the role of an FeIV tetrazene in catalytic aziridination”. Chem. Commun. 2014, 50, 13967.
9. Wu, B.; Hernández Sánchez, R.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M. “Formation of a Heterobimetallic Zirconium/Cobalt Diimido Complexes via a Four-Electron Transformation”. Inorg. Chem. 2014, 53, 10021.
8. Powers, T. M.; Gu, N. X.; Fout, A. R.; Baldwin, A. M.; Hernández Sánchez, R.; Alfonso, D. M.; Chen, Y.-S.; Zheng, S.-L; Betley, T. A. “Synthesis of Open-Shell, Bimetallic Mn/Fe Trinuclear Clusters”. J. Am. Chem. Soc. 2013, 135, 14448.
7. Eames, E.; Hernández Sánchez, R.; Betley, T. A. “Metal atom lability in polynuclear complexes”. Inorg. Chem. 2013, 56, 5006.
6. Kraft, S. J.; Hernández Sánchez, R.; Hock, A. S. “A Remarkably Active Iron Catecholate Immobilized in a Porous Organic Polymer”. ACS Catal. 2013, 3, 826.
5. Wong, L. J.; Hernández Sánchez, R.; Glancy Logan, J.; Zarkesh, R. A.; Ziller, J. W.; Heyduk, A. F. “Disulfide reductive elimination from an iron(III) complex”. Chem. Sci. 2013, 4, 1906.
4. Harris, T. D.; Zhao, Q.; Hernández Sánchez, R.; Betley, T. A. “Expanded Redox Accessibility via Ligand Substitution in an Octahedral Fe6Br6 Cluster”. Chem. Commun. 2011, 47, 6344.
3. Yamazaki, Y.; Hernandez-Sanchez, R.; Haile, S. M. “Cation nonstoichiometry in yttrium-doped barium zirconate: phase behavior, microstructure, and proton conductivity”. J. Mater. Chem. 2010, 20, 8158-8166.
2. Telila, H.; Mamo, T.; Hernandez Sanchez, R. “The Fabrication of nanoparticle CsH2PO4 Electrolyte for Fuel Cell Applications”. Caltech Undergraduate Research Journal 2009, 9 (No. 1), 33 – 39.
1. Yamazaki, Y.; Hernandez-Sanchez, R.; Haile, S. M. “High Total Proton Conductivity in Large-Grained Yttrium-Doped Barium Zirconate”. Chem. Mater. 2009, 21, 2755-2762.
Patents
1. Milton, M.; Cheng, Q.; Yang, Y.*; Nuckolls, C.*; Hernández Sánchez, R.*; Sisto, T.* “Non-Aqueous Flow Batteries”. U.S. Application No. 62/546,967, filed August 17, 2017. Provisional patent.
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University of Pittsburgh, Chevron Science Center. 219 Parkman Ave, Pittsburgh, PA 15260. Office: 1113; Phone: 412-648-4218. raulhs@pitt.edu
© 2018 HS group
© 2018 HS group
