Publications
41. Bucella, D.; Hernández Sánchez, R.; Morrow, J. R.; Pierre, V. C.;* Wilson, J. J.* "Supramolecular inorganic chemistry: from form to function". Supramol. Chem. 2025, DOI: 10.1080/10610278.2025.2510449.
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40. Mirzaei, S.; Khosravi, H.; Hu, X.; Mirzaei, S. M.; Espinoza Castro, V. M.; Wang, X.; Figueroa, N. A.; Chang, T.; Chen, Y.-P.; Prieto Ríos, G.; Gonzalez-Pech, N. I.; Chen, Y.-S.; Hernández Sánchez, R.* "Catching Fullerenes: Synthesis of Molecular Nanogloves". Angew. Chem. Int. Ed. 2025, Just Accepted.
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39. Osei, M. K.;§ Lucht, B.;§ Xu, H.-L.; Valles, A.; Espinoza Castro, V. M.; La, H.; Hernández Sánchez, R.* "Cyclen-Based Octaamine Ligand Supporting the Formation of Dinuclear Metal Compounds". Inorg. Chem. 2025, 64, 6408. §Equal contribution.
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38. Mirzaei, S. M.;§ Mirzaei, S.;§ Espinoza Castro, V. M.; Lawrence, C. S.; Hernández Sánchez, R.* "Dual molecular tweezers extending from a nanohoop". Chem. Commun. 2024, 60, 14236. §Equal contribution.
Article part of the Chem. Commun. 2024 Emerging Investigators |
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37. Khosravi, H.;§ Stevens, V.;§ Hernández Sánchez, R.* "HFIP as a versatile solvent in resorcin[n]arene synthesis". Beilstein J. Org. Chem. 2024, 20, 2469. §Equal contribution.
Article part of the thematic issue "Emerging directions in supramolecular chemistry" |
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36. Osei, M.; Mirzaei, S.; Mirzaei, S. M.; Valles, A.; Hernández Sánchez, R.* "Reversible dioxygen uptake at [Cu4] clusters". Chem. Sci. 2024, 15, 5327.
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35. Osei, M.; Mirzaei, S.; Bogetti, X.; Castro, E.; Rahman, M. A.; Saxena, S.; Hernández Sánchez, R.* "Synthesis of Square Planar Cu4 Clusters". Angew. Chem. Int. Ed. 2022, 61, e202209529.
In connection with: "Introducing... Raúl Hernández Sánchez". Angew. Chem. Int. Ed. 2022, 61, e202213566. |
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34. Mirzaei, S.; Espinoza Castro, V. M.; Hernández Sánchez, R.* "Nonspherical anion sequestration by C-H hydrogen bonding". Chem. Sci. 2022, 13, 2026.
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33. Hernández Sánchez, R.;* Mirzaei, S.; Castro, E. "Carbon-based nanotubes". De Gruyter, 2022.
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32. Mirzaei, S.; Castro, E.; Hernández Sánchez, R.* "Conjugated Molecular Nanotubes". Chem. Eur. J. 2021, 27, 8642.
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31. Castro, E.;§ Mirzaei, S.;§ Hernández Sánchez, R.* "Radially Oriented [n]Cyclo-meta-phenylenes". Org. Lett. 2021, 23, 87.
§Equal contribution. Highlighted in: Periodic TableTalks: The Elements Never Go Out of Style |
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30. Gadjieva, N. A.; Szimai, P.; Sági, O.; Alemany, P.; Conejeros, S.; Paley, D. W.; Hernández Sánchez, R.; Fowler, B.; Náfrádi, B.; Forró, L.; Roy, X. S.; Batail, P.;* Canadell, E.;* Steigerwald, M. L.;* Nuckolls, C.* "Intermolecular Resonance Correlates Electron Pairs Down a Supermolecular Chain: Antiferromagnetism in K-Doped p-Terphenyl". J. Am. Chem. Soc. 2020, 142, 20624.
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29. Mirzaei, S.;§ Castro, E.;§ Hernández Sánchez, R.* "Tubularenes". Chem. Sci. 2020, 11, 8089.
§Equal contribution. Selected for the cover of Chemical Science Volume 11, Issue 31, 21 August 2020. Highlighted in: Chemistry World and ChemistryViews Selected as part of the themed collections: Most popular 2019-2020 materials and energy chemistry articles and 2020 Chemical Science HOT Article Collection (Royal Society of Chemistry) |
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As graduate student and postdoc
28. Liu, T.; Yang, J.; Geyer, F.; Conrad-Burton, F.; Hernández Sánchez, R.; Li, H.; Zhu, X.; Xiao, S.; Nuckolls, C.; Steigerwald, M. “Stringing the Perylene Diimide Bow”. Angew. Chem. Int. Ed. 2020, 59, 14303.
27. Conrad-Burton, F.; Liu, T.; Geyer, F.; Costantini, R.; Schlaus, A.; Spencer, M.; Wang, J.; Hernández Sánchez, R.; Zhang, B.; Xu, Q.; Steigerwald, M.; Xiao, S.; Li, H.; Nuckolls, C.; Zhu, X. "Controlling Singlet Fission by Molecular Contortion". J. Am. Chem. Soc. 2019, 141, 13143.
26. Bartholomew, A. K.;† Teesdale, J. J.; Hernández Sánchez, R.; Malbrecht, B.J.; Juda, C. E.; Ménard, G.; Bu, W.; Iovan, D. A.; Mikhailine, A. A.; Zheng, S.-L.; Sarangi, R.; Wang, S. G.; Chen, Y.-S.; Betley, T.A.* "Exposing the inadequacy of redox formalisms by resolving redox inequivalence within isovalent clusters". Proc. Natl. Acad. Sci. 2019, 116, 15836.
25. Milton, M.; Schuster, N.; Paley, D. W.; Hernández Sánchez, R.; Ng, F.; Steigerwald, M. L.; Nuckolls, C. “Defying Strain in the Synthesis of an Electroactive Bilayer Helicene”. Chem. Sci. 2019, 10, 1029.
24. Hernández Sánchez, R.; Betley, T. A. “Thermally persistent high spin ground states in octahedral iron clusters”. J. Am. Chem. Soc. 2018, 140, 16792.
23. Hernández Sánchez, R.*; Champsaur, A. M.; Paley, D. W.; Choi, B.; Wang, S. G.; Bu, W.; Roy, X.; Chen. Y.-S.;* Steigerwald, M. L.;* Nuckolls, C.* “Electron cartography in clusters”. Angew. Chem. Int. Ed. 2018, 57, 13815.
22. Schuster, N.; Hernández Sánchez, R.; Bukharina, D.; Kotov, N. A.; Berova, N.; Ng, F.; Steigerwald, M. L.; Nuckolls, C. “A Helicene Nanoribbon with Greatly Amplified Chirality”. J. Am. Chem. Soc. 2018, 140, 6235.
21. Zhang, B.;§ Hernández Sánchez, R.;§ Zhong, Y.; Ball, M.; Terban, M. W.; Paley, D.; Billinge, S. J. L.; Ng, F.; Steigerwald, M. L.; Nuckolls, C. “Hollow Organic Semiconductors Assemble into Cellular Semiconductors”. Nat. Commun. 2018, 9, 1957. § = equal contribution.
20. Milton, M.; Cheng, Q.; Yang, Y.;* Nuckolls, C.;* Hernández Sánchez, R.;* Sisto, T.* “Molecular Materials for Nonaqueous Flow Batteries with a High Coulombic Efficiency and Stable Cycling”. Nano Lett. 2017, 17, 7859.
19. Keener, M.; Peterson, M.; Hernández Sánchez, R.; Oswald, V. F.; Wu, G.; Ménard, G.*. “Towards Catalytic Ammonia Oxidation to Dinitrogen: A Synthetic Cycle Using a Simple Manganese Complex”. Chem. Eur. J. 2017, 23, 11479.
18. Amiri, H.; Shepard, K.;* Nuckolls, C.;* Hernández Sánchez, R.* “Single-Walled Carbon Nanotubes: Mimics of Biological Ion Channels”. Nano Lett. 2017, 17, 1204.
17. Lee, H.; Campbell, M. G.; Hernández Sánchez, R.; Börgel, J.; Raynaud, J.; Parker, S. E.; Ritter, T. “Mechanistic Insight Into High-Spin Iron(I)-Catalyzed Butadiene Dimerization”. Organometallics 2016, 35, 2923.
16. Furneaux, A. G.; Piro, N. A.; Hernández Sánchez, R.; Garmigna, K. M.; Fey, N.; Robinson, M. J.; Kassel, W. S.; Nataro, C. “Specroscopic, structural and computational analysis of [Re(CO)3(dippM)Br]n+ (dippM = 1,1’-bis(diiso-propylphosphino)metallocene, M = Fe, n = 0 or 1; M = Co, n = 1)”. Dalton Trans. 2016, 45, 4819.
15. Blass, B. L.; Hernández Sánchez, R.; Decker, V. A.; Robinson, M. J.; Piro, N. A.; Kassel, W. S.; Diaconescu, P. L.; Nataro, C. “Structural, Computational, and Spectroscopic Investigation of [Pd(k3-1,1’-bis(di-tert-butylphosphino)ferrocenediyl)X]+ (X = Cl, Br, I) Compounds”. Organometallics 2016, 35, 462.
14. Hernández Sánchez, R.; Bartholomew, A.; Powers, T.; Ménard, G.; Betley, T. A. “Maximizing electron exchange in a [Fe3] cluster”. J. Am. Chem. Soc. 2016, 138, 2235.
13. Hernández Sánchez, R.; Betley, T. A. “Meta-Atom Behavior in Clusters Revealing Large Spin Ground States”. J. Am. Chem. Soc. 2015, 137, 13949.
12. Hernández Sánchez, R.; Zheng, S.-L.; Betley, T. A. “Ligand Field Strength Mediates Electron Delocalization in Octahedral [(HL)2Fe6(L’)m]n+ Clusters”. J. Am. Chem. Soc. 2015, 137, 11126.
11. Hernández Sánchez, R.; Willis, A. M.; Zheng, S.-L.; Betley, T. A. “Synthesis of Well-Defined Bicapped Octahedral Iron Clusters [(trenL)2Fe8(PMe2Ph)2]n (n = 0, –1)”. Angew. Chem. Int. Ed. 2015, 54, 12009.
10. Cramer, S. A.; Hernández Sánchez, R.; Brakhage, D. F.; Jenkins, D. M. “Probing the role of an FeIV tetrazene in catalytic aziridination”. Chem. Commun. 2014, 50, 13967.
9. Wu, B.; Hernández Sánchez, R.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M. “Formation of a Heterobimetallic Zirconium/Cobalt Diimido Complexes via a Four-Electron Transformation”. Inorg. Chem. 2014, 53, 10021.
8. Powers, T. M.; Gu, N. X.; Fout, A. R.; Baldwin, A. M.; Hernández Sánchez, R.; Alfonso, D. M.; Chen, Y.-S.; Zheng, S.-L; Betley, T. A. “Synthesis of Open-Shell, Bimetallic Mn/Fe Trinuclear Clusters”. J. Am. Chem. Soc. 2013, 135, 14448.
7. Eames, E.; Hernández Sánchez, R.; Betley, T. A. “Metal atom lability in polynuclear complexes”. Inorg. Chem. 2013, 56, 5006.
6. Kraft, S. J.; Hernández Sánchez, R.; Hock, A. S. “A Remarkably Active Iron Catecholate Immobilized in a Porous Organic Polymer”. ACS Catal. 2013, 3, 826.
5. Wong, L. J.; Hernández Sánchez, R.; Glancy Logan, J.; Zarkesh, R. A.; Ziller, J. W.; Heyduk, A. F. “Disulfide reductive elimination from an iron(III) complex”. Chem. Sci. 2013, 4, 1906.
4. Harris, T. D.; Zhao, Q.; Hernández Sánchez, R.; Betley, T. A. “Expanded Redox Accessibility via Ligand Substitution in an Octahedral Fe6Br6 Cluster”. Chem. Commun. 2011, 47, 6344.
3. Yamazaki, Y.; Hernandez-Sanchez, R.; Haile, S. M. “Cation nonstoichiometry in yttrium-doped barium zirconate: phase behavior, microstructure, and proton conductivity”. J. Mater. Chem. 2010, 20, 8158-8166.
2. Telila, H.; Mamo, T.; Hernandez Sanchez, R. “The Fabrication of nanoparticle CsH2PO4 Electrolyte for Fuel Cell Applications”. Caltech Undergraduate Research Journal 2009, 9 (No. 1), 33 – 39.
1. Yamazaki, Y.; Hernandez-Sanchez, R.; Haile, S. M. “High Total Proton Conductivity in Large-Grained Yttrium-Doped Barium Zirconate”. Chem. Mater. 2009, 21, 2755-2762.
27. Conrad-Burton, F.; Liu, T.; Geyer, F.; Costantini, R.; Schlaus, A.; Spencer, M.; Wang, J.; Hernández Sánchez, R.; Zhang, B.; Xu, Q.; Steigerwald, M.; Xiao, S.; Li, H.; Nuckolls, C.; Zhu, X. "Controlling Singlet Fission by Molecular Contortion". J. Am. Chem. Soc. 2019, 141, 13143.
26. Bartholomew, A. K.;† Teesdale, J. J.; Hernández Sánchez, R.; Malbrecht, B.J.; Juda, C. E.; Ménard, G.; Bu, W.; Iovan, D. A.; Mikhailine, A. A.; Zheng, S.-L.; Sarangi, R.; Wang, S. G.; Chen, Y.-S.; Betley, T.A.* "Exposing the inadequacy of redox formalisms by resolving redox inequivalence within isovalent clusters". Proc. Natl. Acad. Sci. 2019, 116, 15836.
25. Milton, M.; Schuster, N.; Paley, D. W.; Hernández Sánchez, R.; Ng, F.; Steigerwald, M. L.; Nuckolls, C. “Defying Strain in the Synthesis of an Electroactive Bilayer Helicene”. Chem. Sci. 2019, 10, 1029.
24. Hernández Sánchez, R.; Betley, T. A. “Thermally persistent high spin ground states in octahedral iron clusters”. J. Am. Chem. Soc. 2018, 140, 16792.
23. Hernández Sánchez, R.*; Champsaur, A. M.; Paley, D. W.; Choi, B.; Wang, S. G.; Bu, W.; Roy, X.; Chen. Y.-S.;* Steigerwald, M. L.;* Nuckolls, C.* “Electron cartography in clusters”. Angew. Chem. Int. Ed. 2018, 57, 13815.
22. Schuster, N.; Hernández Sánchez, R.; Bukharina, D.; Kotov, N. A.; Berova, N.; Ng, F.; Steigerwald, M. L.; Nuckolls, C. “A Helicene Nanoribbon with Greatly Amplified Chirality”. J. Am. Chem. Soc. 2018, 140, 6235.
21. Zhang, B.;§ Hernández Sánchez, R.;§ Zhong, Y.; Ball, M.; Terban, M. W.; Paley, D.; Billinge, S. J. L.; Ng, F.; Steigerwald, M. L.; Nuckolls, C. “Hollow Organic Semiconductors Assemble into Cellular Semiconductors”. Nat. Commun. 2018, 9, 1957. § = equal contribution.
20. Milton, M.; Cheng, Q.; Yang, Y.;* Nuckolls, C.;* Hernández Sánchez, R.;* Sisto, T.* “Molecular Materials for Nonaqueous Flow Batteries with a High Coulombic Efficiency and Stable Cycling”. Nano Lett. 2017, 17, 7859.
19. Keener, M.; Peterson, M.; Hernández Sánchez, R.; Oswald, V. F.; Wu, G.; Ménard, G.*. “Towards Catalytic Ammonia Oxidation to Dinitrogen: A Synthetic Cycle Using a Simple Manganese Complex”. Chem. Eur. J. 2017, 23, 11479.
18. Amiri, H.; Shepard, K.;* Nuckolls, C.;* Hernández Sánchez, R.* “Single-Walled Carbon Nanotubes: Mimics of Biological Ion Channels”. Nano Lett. 2017, 17, 1204.
17. Lee, H.; Campbell, M. G.; Hernández Sánchez, R.; Börgel, J.; Raynaud, J.; Parker, S. E.; Ritter, T. “Mechanistic Insight Into High-Spin Iron(I)-Catalyzed Butadiene Dimerization”. Organometallics 2016, 35, 2923.
16. Furneaux, A. G.; Piro, N. A.; Hernández Sánchez, R.; Garmigna, K. M.; Fey, N.; Robinson, M. J.; Kassel, W. S.; Nataro, C. “Specroscopic, structural and computational analysis of [Re(CO)3(dippM)Br]n+ (dippM = 1,1’-bis(diiso-propylphosphino)metallocene, M = Fe, n = 0 or 1; M = Co, n = 1)”. Dalton Trans. 2016, 45, 4819.
15. Blass, B. L.; Hernández Sánchez, R.; Decker, V. A.; Robinson, M. J.; Piro, N. A.; Kassel, W. S.; Diaconescu, P. L.; Nataro, C. “Structural, Computational, and Spectroscopic Investigation of [Pd(k3-1,1’-bis(di-tert-butylphosphino)ferrocenediyl)X]+ (X = Cl, Br, I) Compounds”. Organometallics 2016, 35, 462.
14. Hernández Sánchez, R.; Bartholomew, A.; Powers, T.; Ménard, G.; Betley, T. A. “Maximizing electron exchange in a [Fe3] cluster”. J. Am. Chem. Soc. 2016, 138, 2235.
13. Hernández Sánchez, R.; Betley, T. A. “Meta-Atom Behavior in Clusters Revealing Large Spin Ground States”. J. Am. Chem. Soc. 2015, 137, 13949.
12. Hernández Sánchez, R.; Zheng, S.-L.; Betley, T. A. “Ligand Field Strength Mediates Electron Delocalization in Octahedral [(HL)2Fe6(L’)m]n+ Clusters”. J. Am. Chem. Soc. 2015, 137, 11126.
11. Hernández Sánchez, R.; Willis, A. M.; Zheng, S.-L.; Betley, T. A. “Synthesis of Well-Defined Bicapped Octahedral Iron Clusters [(trenL)2Fe8(PMe2Ph)2]n (n = 0, –1)”. Angew. Chem. Int. Ed. 2015, 54, 12009.
10. Cramer, S. A.; Hernández Sánchez, R.; Brakhage, D. F.; Jenkins, D. M. “Probing the role of an FeIV tetrazene in catalytic aziridination”. Chem. Commun. 2014, 50, 13967.
9. Wu, B.; Hernández Sánchez, R.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M. “Formation of a Heterobimetallic Zirconium/Cobalt Diimido Complexes via a Four-Electron Transformation”. Inorg. Chem. 2014, 53, 10021.
8. Powers, T. M.; Gu, N. X.; Fout, A. R.; Baldwin, A. M.; Hernández Sánchez, R.; Alfonso, D. M.; Chen, Y.-S.; Zheng, S.-L; Betley, T. A. “Synthesis of Open-Shell, Bimetallic Mn/Fe Trinuclear Clusters”. J. Am. Chem. Soc. 2013, 135, 14448.
7. Eames, E.; Hernández Sánchez, R.; Betley, T. A. “Metal atom lability in polynuclear complexes”. Inorg. Chem. 2013, 56, 5006.
6. Kraft, S. J.; Hernández Sánchez, R.; Hock, A. S. “A Remarkably Active Iron Catecholate Immobilized in a Porous Organic Polymer”. ACS Catal. 2013, 3, 826.
5. Wong, L. J.; Hernández Sánchez, R.; Glancy Logan, J.; Zarkesh, R. A.; Ziller, J. W.; Heyduk, A. F. “Disulfide reductive elimination from an iron(III) complex”. Chem. Sci. 2013, 4, 1906.
4. Harris, T. D.; Zhao, Q.; Hernández Sánchez, R.; Betley, T. A. “Expanded Redox Accessibility via Ligand Substitution in an Octahedral Fe6Br6 Cluster”. Chem. Commun. 2011, 47, 6344.
3. Yamazaki, Y.; Hernandez-Sanchez, R.; Haile, S. M. “Cation nonstoichiometry in yttrium-doped barium zirconate: phase behavior, microstructure, and proton conductivity”. J. Mater. Chem. 2010, 20, 8158-8166.
2. Telila, H.; Mamo, T.; Hernandez Sanchez, R. “The Fabrication of nanoparticle CsH2PO4 Electrolyte for Fuel Cell Applications”. Caltech Undergraduate Research Journal 2009, 9 (No. 1), 33 – 39.
1. Yamazaki, Y.; Hernandez-Sanchez, R.; Haile, S. M. “High Total Proton Conductivity in Large-Grained Yttrium-Doped Barium Zirconate”. Chem. Mater. 2009, 21, 2755-2762.
Patents
3. Arora, S.; Mirzaei, S.; Espinoza Castro, V. M.; Hernández Sánchez, R.* “Compositions comprising macrocyclic hosting moieties”. U.S. Non-Provisional Patent US 18/101,092 filed on January 24, 2023.
2. Castro, E.; Mirzaei, S.; Hernández Sánchez, R.* “Synthesis of Nanotubular Molecules”. U.S. Non-Provisional Patent US 17/386,100 filed on July 27, 2021.
1. Milton, M.; Cheng, Q.; Yang, Y.*; Nuckolls, C.*; Hernández Sánchez, R.*; Sisto, T.* “Non-Aqueous Flow Batteries”. US 16/792,501 and International Publication No. WO 2019/036633 A1.
2. Castro, E.; Mirzaei, S.; Hernández Sánchez, R.* “Synthesis of Nanotubular Molecules”. U.S. Non-Provisional Patent US 17/386,100 filed on July 27, 2021.
1. Milton, M.; Cheng, Q.; Yang, Y.*; Nuckolls, C.*; Hernández Sánchez, R.*; Sisto, T.* “Non-Aqueous Flow Batteries”. US 16/792,501 and International Publication No. WO 2019/036633 A1.
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Rice University, 6100 Main St., Houston, TX 77005. +1 (713) 348-5694. Ralph S. O’Connor Building for Engineering Science
344 and 348. [email protected]
© 2018 HS group
344 and 348. [email protected]
© 2018 HS group
